Sunday, September 28, 2008

204a: Paella Valenciana

This is a preview of show 204, which is something of an unfinished work-in-progress while I try to figure out how to pad out the last ten minutes. Paella happens to have a bit of sentimental value as a dish, as it was one of the first dishes I learned to cook out of one of the first cookbooks I bought for myself, Catalan Cuisine by Colman Andrews (Collier/Macmillan, 1988). It was my favorite of a number of dishes I used to cook with my grandfather when he lived with us for the last couple of years of his life, and although I don't make it much anymore, paella is still one of my signature dishes.

This particular version is one I did for the very first time on a grill, something I'd never done before. It's very basic -- just chicken (and, if you're so inclined, rabbit) and green beans, with short grain rice, cooked over a grill. You can certainly add whatever shellfish you wish, but the original Paella Valenciana is an inland dish. The crust on the bottom -- known as socarrat in Catalan -- is a desired part of the dish, and this paella being done on the grill gave me my very first opportunity to taste it.
  • 500g short grain rice (Calasparra, Arborio, or Japanese short-grain)
  • 1 L chicken broth
  • 250 g green beans
  • 2-3 plum tomatoes, chopped
  • 1 kg chicken breast, cubed (or, half and half chicken and rabbit)
  • 1 onion, chopped
  • olive oil
  • kosher salt
  • pinch saffron
  1. Preheat grill. (If using charcoal, you may want to start an extra chimney starter after the fire is going.)
  2. Sofrito: Add some olive oil to the pan and then add the onions with a sprinkle of salt. Cook until onions are translucent and beginning to brown, then add the chopped tomatoes and cook until they start to become jammy.
  3. Push the sofrito aside and put the chicken (and, if using, rabbit) in a puddle of oil on the other side of the pan. Cook the meat until it's just cooked through, then toss with the sofrito.
  4. Add the chicken broth, then add green beans and saffron and correct for salt. (At this point you may need to add the new batch of charcoal.) Set the fire up for indirect heat and add the rice when the broth comes to a boil.
  5. Cook at a simmer for 15-20 minutes, uncovered, until the rice is tender and a crust begins to form on the bottom.
  6. Serve with wine and bread (or, as they do in Valencia, scallions).

Justus V. Liebig, Would You Please Go Now?

A recent trip to visit a friend at the Cape Cod Hospital proved interesting from a culinary standpoint. See, i'm kind of a compulsive recipe collector, and it turns out that catering behemoth Sodexho, who operates the CCH's cafeteria with a surprisingly high level of quality, publishes recipe cards for patients. Pretty sensible, i think -- people frankly eat like crap in this country, so a hospital cafeteria providing healthy recipes is a pretty obvious step. (Pay no attention to the burger bar i'm writing this in.) Anyway, the first card is a listing of "alternate" cooking techniques. I quotate "alternate" because other than deep-frying and grilling, it's pretty much a roadmap to Cooking 101. Well, except for one thing -- it's 2008 and this supposedly-informative card is telling me that searing "seals in juices."

So let's talk about Justus von Liebig for a bit. He was one of the 19th century's big pioneers of kitchen science, and a contemporary, more or less, of Louis Pasteur. He was an interesting fellow -- a generalist chemist (in fact one of the founders of modern organic chemistry), a university professor, and an entrepreneur; among other accomplishments, he was the discoverer of nitrogen-based fertilizer and one of the three responsible for discovering chloroform, as well as the founder of one of the most important chemistry journals in the world (Liebigs Annalen der Chemie, later incorporated into the European Journal of Organic Chemistry) and the creator of a process for industrial manufacture of beef extract that led to the creation of the modern bouillion cube. But after all this, he's probably best remembered for the idea that searing meat sears in the juices. Yeah... not so much.

Not that long ago I acquired a copy of Paul Aratow's translation of La bonne cuisine de Mme. E. Saint-Ange (Ten Speed Press, 2005, ISBN 9781580086059), one of the great French home cookbooks of the early 20th century, which through its influence on people such as Aratow (the original chef de cuisine at Chez Panisse), Julia Child, and Madeleine Kamman, may have been the biggest influence on recent American cuisine of any book of its time. Mme. Saint-Ange mentions it. Escoffier supposedly mentioned it. Lots of cookbooks still do. I have no bloody idea why -- as Harold McGee pointed out in the oft-cited-here On Food and Cooking, this is a total falsehood. To explain why, we have to understand a little about the structure of skeletal muscle, which after all makes up the overwhelming majority of American meat consumption. (We, as a country, are not fond of organ meats. That's just how it is.)

Skeletal muscle is made up of a bundle of fibers in which each fiber is a further bundle of long, multinucleate cells containing networks of two proteins, known as actin and myosin, which interact in a sort of telescoping manner (you can check the Wikipedia article). When cooked, many of the proteins within the meat denature and coagulate in very much the same process as I explained in my last article on eggs; in the particular case of actin/myosin bundles, however, they don't denature so much as contract. This response to heating causes the cell fluids to leak out and move towards the surface of the cut meat; as a result, the overall process causes the meat to physically shrink as it cooks. When these juices reach the surface on a grill or a frying pan, they hit the incoming heat and, essentially, caramelize like sugar in a Maillard reaction. The resulting dark, crusty substance is what becomes known as fond when it sticks to the frying pan (and is sometimes deglazed with wine or stock to create a pan sauce). Liebig believed that the fond was actually waterproof and was capable of keeping the meat's juices inside rather than having them gush out onto the pan.

Well, modern cookbooks do still recommend the sear, but solely because of its flavor-building properties -- the simple fact is, if you throw a steak in a frying pan, the juices will continue to exude from the meat as it cooks, a point that's readily observed just from the sizzle (i.e. boiling water) you keep hearing up until the moment the steak comes out of the pan. That juice will keep coming out of your steak until it has the approximate consistency of a hockey puck, at which point you will be savagely attacked by a professional chef for wasting the life of an innocent animal on an inedible meal. So what does one do, if Liebig's technique doesn't work?

The easiest way with steaks is just not to cook them past medium if you can at all help it. Even my well-done-loving mother is just fine with a medium-cooked steak if it's got a nice pan sauce on it. But there's other things you can do if you're not making steak. For example, with a roast, the accepted technique is to cook the meat (beef or otherwise) at a relatively low temperature for a long period of time, creating fond at the beginning or end with either a pan searing or a blast of high heat from the oven element. (Poultry can take this a step further; Chinese cooks actually steam chicken and especially duck (in this case it helps render duck's copious amounts of subcutaneous fat) before finishing off with high heat, and Chinese-American cooks have even adapted it to the Thanksgiving turkey. I did it once by accident -- easily one of the best turkeys ever.) Some meats (particularly pork, turkey, and chicken) can be brined -- the salt water is absorbed into the meat by osmotic pressure. A braise or stew begins with a sear, but incorporates the meat juices into its own sauce, which can be used as a gravy for serving. It's in barbecue, though, that we find the cleverest trick of all: collagen.

Meat connective tissue has two major proteins in it -- collagen (the same as in skin) and elastin. Elastin you can't do anything with -- it's rubbery, plasticky stuff that makes up a large part of what butchers refer to as silverskin, and it only toughens with cooking. Collagen is something different though -- give it enough heat, and it denatures into gelatin, which drastically changes the whole picture. While you normally think of gelatin as a wobbly solid, usually fruit (and possibly vodka) flavored, it turns out that for braises and barbecues, gelatin is a critical part of the final mouthfeel, retaining fluid within the meat and lubricating the dried-out muscle fibers that would otherwise go the hockey puck route. In fact, French pot roasts (often referred to as "daubes") often add extra gelatin, usually in the form of a calf's or pig's foot, but also just straight out of the envelope in some recipes, for precisely this purpose. Many older recipes add "larding" -- threading of sticks of pork fat (lardons) through a piece of cheap or low-quality meat to replace fat marbling that would be in a higher-quality cut, producing similar results to gelatin as the fat melts. This is not usually necessary in American meat, which is generally of much higher quality than European, though rumor has it kids are far more likely to dig in when you tell them that the lardons are actually worms. And in extreme cases, like pulled pork, you can punt on the issue entirely -- shred the meat and douse it in some kind of sauce.

So Liebig was flat out wrong, and for some mysterious reason, even though his hypothesis was discredited decades ago, it continues to be propagated in both home kitchens and in the literature. But it doesn't mean it's a bad idea -- the flavor-building attributes of searing are vitally necessary to a palatable piece of grilled, roasted or sauteed (or even braised) meat. Liebig made a great many contributions to modern science, but this is one area he probably should have done just a bit more work.

I close with a story. There's a restaurant in my town (I won't name names as they've changed management since this happened and have apparently gotten better) that used to advertise a T-bone steak special. It was a cheap special and a thin steak, but a half-inch T-bone is still a good-sized piece of meat, so I tried it once on a day when I was feeling rich. It was terrible -- the meat was the same grey color I associate with meat tenderizer, and the side of sauteed onions were barely any more cooked than the onions on top of a pizza get, and not even close to the seductive sweetness of the fairground onions they throw on sausage subs. The meal was edible, but considering it was a local joint with a reputation to uphold, the utter incompetence of the grill person produced something barely worthy of a low-rent steakhouse chain like the Ponderosa. I've no idea how they lasted as long as they did under that management.

Wednesday, September 17, 2008

The Tangled Bank

I appear to be slacking on my trackbacks. Thanks very much to PZ Myers of Pharyngula @scienceblogs.com for accepting me to two issues in a row of his blog carnival, The Tangled Bank, and I look forward to contributing a little further, however small, to the body of knowledge.

Tangled Bank #114 at sciencemadecool.com

Tangled Bank #113 at En Tequila Es Verdad

Sunday, September 14, 2008

The incredible edible egg

Is it time for another science post? So be it. Today's Iron Blogger ingredient is... EGGS!!!!

First, I have to admit that I have something of an aversion to straight-up eggs in any form -- when I make eggs, they have to be heavily adulterated, with vegetables and cheese and meat and all kinds of other goodies. So I won't go into great detail about them... after this short play-along-at-home demo of scrambled eggs.

See, we're talking about egg proteins specifically here, and we're going to start with a couple of eggs, scrambled, with some salt, pepper, and a couple of tablespoons of milk if you wish. (If you're me, you'll probably want a handful of shredded sharp cheddar or gruyere to throw on at the end as well.) Get a small, preferably nonstick frying pan (always nonstick for eggs, unless you're an old hand at omelet making). Scramble up the eggs and heat the pan on medium high, then drop in a pat of butter or a splash of olive oil. Pour the eggs in, and begin stirring with a wooden spoon or a silicone spatula. As you stir and scrape the cooked egg off the bottom, they'll form curds of egg protein. Stir just until the egg is completely coagulated, then toss some cheese on top if you like and serve. Or, for the sake of the experiment, you could let it go just a bit longer, at which point liquid will start gushing out of the scrambled eggs and you'll have a swamp of cooked eggs in vaguely sulfurous dishwater. So what's happening?

Well, one of the things that makes eggs so useful as a culinary ingredient (apart from their high-powered energy/nutrition punch, which is just fine as long as you don't overindulge) is their proteins. Egg proteins are rather easy to denature, but readily recoagulate into various other shapes. In the scrambled egg case, you're taking a protein suspension, denaturing the natural crosslinks in the proteins therein, and applying heat to cause them to reassemble into a more-or-less solid gel. Overcooking the eggs causes the gel to break down and cause the water in the egg (and milk, if you added that) to squeeze out into the pan, causing the egg proteins to coagulate further into a dry and rubbery mass. (At this point, you're going to need the cheese anyway.) In fact, eggs are so useful, both as dishes unto themselves and as ingredients in other dishes, that at least one cookbook, Delia Smith's How To Cook, starts off with an entire chapter on cooking eggs; Shirley Corriher's CookWise and Julia Child's first great work, Mastering the Art of French Cooking, both include chapters on eggs as well. That was the opening act. Now the headliner: sponge cake.

You will find in many cookbooks a recipe for a simple sponge cake called a Génoise. This is one of the most basic recipes in the baker's repertoire -- it is a whole egg sponge cake, which depends for its lift and structure entirely on eggs and air, with no assistance from baking powder or yeast. I'm not going to get into the details of the recipe; instead I'll link you to Jacques Torres' recipe on foodnetwork.com and explain a little about what's going on. First, the ingredients:
  • Pastry flour: low-gluten flour; provides starch and bulk to the recipe without the gluten crosslinks that would make it tough and bready. All-purpose flour can be used as well, though it needs a bit more care to avoid gluten development.
  • Sugar: for flavor and mouthfeel, and may also aid the foaming process during the egg-beating step.
  • Eggs: Structure. Not only does the foam lighten the mix and allow it to be cakey, it also literally holds the entire cake together, holding the starch particles from the flour in a matrix of egg proteins.
  • Egg yolks or butter: Mostly for mouthfeel. You won't find this in every génoise, and in fact some French recipes are rather leaner than Torres'.
  • Honey: This is an unusual ingredient, and I'm not 100% sure why it's here. My best guess: génoise makes for a rather dry cake, and is usually soaked in a syrup. My feeling is that the honey, being hygroscopic, is meant to moisten the cake a bit so it's a little more agreeable to American tastes in a dry state.
The first stage here is the key (and incidentally in my limited cake-making experience I find the double boiler overkill; the egg-sugar mix comes up to temperature in a perfectly timely fashion over a bowl of hot water, and can be done right in the mixer bowl that way) -- the heat aids in the denaturing of the proteins (other sponge cakes usually separate the eggs and beat the whites alone) and allows them to set ever so slightly into a foam stable enough to accept the flour being folded in. Essentially, the egg has reached a point not entirely unlike a plastic foam -- strings of proteins crosslinked into a net, creating a very high surface tension within the egg fluids and allowing them to trap large quantities of air. It is often said that the egg acts as the leavening in this case; this is not strictly true. The air (and to a lesser extent water vapor from the eggs) is really what provides the leavening, by expanding (and boiling) in the oven and causing the bubbles trapped in the egg foam to expand. But the cake won't rise without the egg protein bubbles.

At this point, the folding step comes in -- the flour is carefully sprinkled onto the egg foam and combined with the foam in such a way as to break as few of these bubbles as possible. There is a third step that Torres' recipe bypasses -- if you use melted butter, you may want to temper it first. Essentially, this constitutes mixing a part of the cake batter into the melted butter and combining them before folding that mixture back into the main body, the same way you did the flour. The key here is that the tempering step both emulsifies the butter (so it won't clump up as it cools and leave big greasy holes in the cake) and cools it so it doesn't scramble the eggs and ruin the structure of the cake.

Finally, the baking step. At this point we've come around to the same point as we did with our finished scrambled eggs -- we want the egg proteins to coagulate within the batter, solidifying the batter and trapping the air that we worked so hard to incorporate. The trapped gases within the batter will expand as the batter heats in the oven, causing the cake to increase in volume and lighten. The end result is perhaps a bit bland, but that's no thang -- soak it with some kind of flavored syrup, sandwich some favorite fruit preserves between the layers, and then just cover the whole thing in whipped cream or buttercream frosting, and you've got Cake 101.

After all this, it's worth pointing out that if you have baking powder or some other chemical leavening, you don't have to go through all the trouble of foaming the eggs; you can just as easily use a quickbread-type recipe that will create the bubbles for you. (In fact, a quickbread method is a good way to make breads out of grains such as barley or oats that don't have significant amounts of gluten.) And what if you can't or don't eat eggs? Well, xanthan gum, a goopy polysaccharide derived from a sugar fermentation process by a bacterium called Xanthomonas campestris, is used rather often for creating gluten-free breads, as it's a reasonably good substitute for gluten with some other grains. Tofu, agar, cocoa butter, and a number of other ideas have also been floated as substitutes; check this BBC article on vegan baking for more details and recipes. The methods for dealing with mouthfeel and structure issues are many and varied.

So there's a taste of what eggs do in kitchens. There's much, much more written on the subject, far more than can be covered in one (already rather overlong) blog post. I think, though, that this ought to cover the basics.

Further reading:
  • Child, Julia and Simone Beck, Mastering the Art of French Cooking, Volume 2. New York: Knopf, 1972. Child and Beck's second collaboration, Mastering 2 contains much information on the practicalities of French baking, and possibly the definitive English-language recipe for Génoise cake, as well as much wisdom on bread making learned directly from France's master of bread, Raymond Calvel.
  • Cook's Illustrated Magazine, Baking Illustrated. Brookline, MA: America's Test Kitchen, 2003. In which CI, the magazine of record for kitchen nerdistry, turns its attention to the ins and outs of baking. While not as scientific as Corriher or McGee, it is absolutely loaded with rubber-hits-the-road practical information.
  • Corriher, Shirley, CookWise. New York: William Morrow & Co, 1997, ISBN 0688102298. The masterwork of a food scientist who specializes in practical applications for home cooks. Has an entire chapter on eggs, after going into great detail about baking. Her long-delayed sequel, BakeWise, might ship this year. Maybe.
  • McGee, Harold, On Food and Cooking, 2ed. New York: Scribner, 2004, ISBN 0684800012. The microphotographs of various food structures, as well as many diagrams, make this an invaluable visual aid.

Wednesday, September 10, 2008

Marmitako de atún

Eggs post is coming, I promise. Still researching it, as it's proving to be a wider scope than I was originally thinking.

Anyway, one of the fun things about searching for recipes on the Internet is finding recipes on some country's official tourism site. A lot of countries like to do this (as do a lot of regions within countries), just to show off their local products and recipes. For my part, I've found one of the more interesting sites to be Turespaña (www.spain.info), Spain's national site, which happens to have the equivalent of a good-sized Spanish regional cookbook floating around on it. The recipes occasionally use odd or highly local ingredients that you won't necessarily be able to find overseas, and are sometimes vastly simplified, but if you can't afford something like Simone Ortega's 1080 Recipes or Penelope Casas' The Food and Wine of Spain, it's a great place to go for inspiration. Given that Spanish food is definitely on an upswing in popularity in the last ten years, you should definitely bookmark it.

Which brings me to an interesting dish I found while surfing around there: sorropotún. It comes from Cantabria, a part of Spain on the Bizkaia coast wedged in between Asturias and the Basque Country. This is the part of Spain where ancient Celtic heritage remains strongest, and sorropotún certainly seems to reflect it -- the simplest recipe I could find, the one from Turespaña, is almost exactly like an Irish stew, with bonito or tuna instead of lamb or beef. It looks pretty good, but when first proposed to my intended audience, it didn't get them juiced. With a little more poking around (particularly in 1080 and Casas) I figured out that it was a simplification of a Basque-style marmitako, a type of stew with a name simply meaning "cooked in a stockpot" (marmite in French). Though lacking easy access to bonito in any form except dried, I did manage to scrape together about a pound of albacore filets and a yellowtail stake to come up with a very good approximation of a red tuna marmitako. I think it's one of my most successful culinary experiments ever.

This will serve between 4-6 people. Feel free to experiment; at the end of the day it's fisherman food, and you can use pretty much any firm fish in it, not just tuna and family. For the fish stock, I used Japanese instant dashi, but you can use anything of that sort. Measurements are metric, because I can. The peas are optional, but only because I forgot them when I actually made it.
  • 600g tuna, albacore, or bonito steaks, cut in 2cm dice
  • 1 liter fish stock or clam broth
  • 2 onions, quartered and sliced thin
  • 2-3 plum tomatoes, peeled and chopped
  • 1 red bell pepper, chopped
  • 3 cloves garlic, crushed or minced
  • 1 kg potatoes, diced (I mixed russet and waxy)
  • 200g frozen peas (optional)
  • olive oil
  • salt, pepper, bay leaf, and chopped parsley to taste
  1. Salt and sear the tuna cubes in olive oil, and set aside.
  2. Sofrito: Heat some olive oil in the pot and wilt the onions with some salt; once they're soft and translucent, add the garlic, cook quickly, then the tomatoes and chopped bell pepper. Correct for seasoning and cook till the tomatoes are starting to get jammy.
  3. Add the potatoes and the fish stock, as well as the bay leaves and parsley. Bring just to a boil and then drop to a simmer for 20-30 minutes.
  4. When the potatoes are almost cooked, add the tuna cubes (and, if using, the peas) back to the pot and heat through, about 10-15 minutes.
  5. Serve in a bowl with crusty bread and Spanish wine or pilsener-type beer.

Saturday, September 6, 2008

Spare me: can anyone explain how they price bottled water?

There's a long tradition going back to, oh, the late 19th century of bottling and shipping water. However, until about the mid-1980s, it was mostly spring waters and naturally carbonated mineral waters from various parts of the world; it wasn't until the widespread scandals of contaminated municipal water supplies in the late 1980s that bottled water became an industry. (You may wish to go watch or read A Civil Action as a reminder that it wasn't just a hysterical reaction -- industry-contaminated aquifers were killing people.) I like to think, though with little real justification, that since those days municipal water systems have tightened up on lead and contaminates, but it's still a problem in some places; here on Cape Cod, for example, perchlorates and other chemicals from military activities at Camp Edwards are a big deal for the towns of Sandwich, Bourne, and Falmouth, and even in my own town of Yarmouth there's the worry that as freshwater aquifers are drained, salt water could be invading the water table. I drink the municipal water; my parents prefer the bottled stuff.

I will say one thing. Being able to grab a sports bottle of water off a refrigerator shelf on a hot day is certainly convenient. While you shouldn't store water in a used spring water bottle, they're usually good for two or three fills until they're ready to trash. What I don't get is the pricing structure of bottled water -- it seems completely arbitrary. If I go into a typical convenience store, there's usually three or four brands of bottled and filtered tap water -- around here, Poland Spring, Dasani (from Coke), Aquafina (from Pepsi), and usually a house brand. Base price for a bottle between half a liter and 20oz is usually between a buck and a buck and a quarter. For some reason, the filtered tap brands from the big soda companies actually cost more than the brand name spring waters. The real kicker, though, is that a gallon of water is usually not that much more than a single-sized liter bottle, and will actually be cheaper when you go to the supermarket.

Between the absurdist pricing structure and the massive energy outlay it takes to cart around truckloads of bottled water, I switched to using reusable water bottles a year or two ago. I still buy bottled water occasionally, but I've tried to cut way back on my purchases of single-serving bottles. What I want to know is this: why can't convenience stores put a coin-op water dispenser in? A quarter a gallon, maybe a dime for a liter. The machines exist, but they're not nearly common enough. (One of the few I can think of off the top of my head is out in the middle of a mall parking lot. Not the most convenient site for a water refill.) Can we make this happen?

Next post will be another food science post, this one on egg matrices and quick breads. Stay tuned.